Combining the incompatible: Block copolymers sequentially displaying amines and activated esters and
Get the full paper here: Polym. Chem. 6, 476 (2015). We present the facile synthesis and orthogonal functionalization of diblock copolymers containing two mutually incompatible segments, i.e. primary amines and activated esters, that are displayed chronologically and synthesized by consecutive radical addition fragmentation transfer polymerization (RAFT) of suitably modified monomers. Post-polymerization modification of the active ester moieties with functionalized triethylen